Kaix
07-27-2006, 03:27 PM
pH
pH refers to water being either an acid, base, or neither (neutral). A pH of 7 is said to be neutral, a pH below 7 is “acidic” and a pH above 7 is “basic” or “alkaline”. Like the Richter scale used to measure earthquakes, the pH scale is logarithmic. A pH of 5.5 is 10 times more acidic than water at a pH of 6.5. Thus, changing the pH by a small amount (suddenly) is more of a chemical change (and more stressful to fish!) than might first appear.
To a fishkeeper, two aspects of pH are important. First, rapid changes in pH are stressful to fish and should be avoided. Changing the pH by more than .3 units per day is known to stress fish. Thus, you want the pH of your tank to remain constant and stable over the long haul. Second, fish have adapted to thrive in a (sometimes narrow) pH range. You want to be sure that your tank's pH matches the specific requirements of the fish you are keeping.
Most fish can adjust to a pH somewhat outside of their optimal range. If your water's pH is naturally within the range of 6.5 to 7.5, you will be able to keep most species of fish without any problems. If your pH lies within this range, there is probably no need to adjust it upward or downward.
Buffering Capacity (KH, Alkalinity)
Buffering capacity refers to water's ability to keep the pH stable as acids or bases are added. pH and buffering capacity are intertwined with one another; although one might think that adding equal volumes of an acid and neutral water would result in a pH halfway in between, this rarely happens in practice. If the water has sufficient buffering capacity, the buffering capacity can absorb and neutralize the added acid without significantly changing the pH. Conceptually, a buffer acts somewhat like a large sponge. As more acid is added, the “sponge” absorbs the acid without changing the pH much. The “sponge's” capacity is limited however; once the buffering capacity is used up, the pH changes more rapidly as acids are added.
Buffering has both positive and negative consequences. On the plus side, the nitrogen cycle produces nitric acid (nitrate). Without buffering, your tank's pH would drop over time (a bad thing). With sufficient buffering, the pH stays stable (a good thing). On the negative side, hard tap water often almost always has a large buffering capacity. If the pH of the water is too high for your fish, the buffering capacity makes it difficult to lower the pH to a more appropriate value. Naive attempts to change the pH of water usually fail because buffering effects are ignored.
In freshwater aquariums, most of water's buffering capacity is due to carbonates and bicarbonates. Thus, the terms “carbonate hardness” (KH), “alkalinity” and “buffering capacity” are used interchangeably. Although technically not the same things, they are equivalent in practice in the context of fishkeeping. Note: the term “alkalinity” should not be confused with the term “alkaline”. Alkalinity refers to buffering, while alkaline refers to a solution that is a base (i.e., pH > 7).
How much buffering does your tank need? Most aquarium buffering capacity test kits actually measure KH. The larger the KH, the more resistant to pH changes your water will be. A tank's KH should be high enough to prevent large pH swings in your tank over time. If your KH is below roughly 4.5 dH, you should pay special attention to your tank's pH (e.g, test weekly, until you get a feel for how stable the pH is). This is ESPECIALLY important if you neglect to do frequent partial water changes. In particular, the nitrogen cycle creates a tendency for an established tank's pH to decrease over time. The exact amount of pH change depends on the quantity and rate of nitrates produced, as well as the KH. If your pH drops more than roughly two tenths of a point over a month, you should consider increasing the KH or performing partial water changes more frequently. KH doesn't affect fish directly, so there is no need to match fish species to a particular KH.
Note: it is not a good idea to use distilled water in your tank. By definition, distilled water has essentially no KH. That means that adding even a little bit of acid will change the pH significantly (stressing fish). Because of its instability, distilled (or any essentially pure water) is never used directly. Tap water or other salts must first be added to it in order to increase its GH and KH.
There only some cases where you should use distilled water or RO water in your freshwater tank, if you are keeping fish like discus where they need to have GH as low as 30 to 50 GH.
pH refers to water being either an acid, base, or neither (neutral). A pH of 7 is said to be neutral, a pH below 7 is “acidic” and a pH above 7 is “basic” or “alkaline”. Like the Richter scale used to measure earthquakes, the pH scale is logarithmic. A pH of 5.5 is 10 times more acidic than water at a pH of 6.5. Thus, changing the pH by a small amount (suddenly) is more of a chemical change (and more stressful to fish!) than might first appear.
To a fishkeeper, two aspects of pH are important. First, rapid changes in pH are stressful to fish and should be avoided. Changing the pH by more than .3 units per day is known to stress fish. Thus, you want the pH of your tank to remain constant and stable over the long haul. Second, fish have adapted to thrive in a (sometimes narrow) pH range. You want to be sure that your tank's pH matches the specific requirements of the fish you are keeping.
Most fish can adjust to a pH somewhat outside of their optimal range. If your water's pH is naturally within the range of 6.5 to 7.5, you will be able to keep most species of fish without any problems. If your pH lies within this range, there is probably no need to adjust it upward or downward.
Buffering Capacity (KH, Alkalinity)
Buffering capacity refers to water's ability to keep the pH stable as acids or bases are added. pH and buffering capacity are intertwined with one another; although one might think that adding equal volumes of an acid and neutral water would result in a pH halfway in between, this rarely happens in practice. If the water has sufficient buffering capacity, the buffering capacity can absorb and neutralize the added acid without significantly changing the pH. Conceptually, a buffer acts somewhat like a large sponge. As more acid is added, the “sponge” absorbs the acid without changing the pH much. The “sponge's” capacity is limited however; once the buffering capacity is used up, the pH changes more rapidly as acids are added.
Buffering has both positive and negative consequences. On the plus side, the nitrogen cycle produces nitric acid (nitrate). Without buffering, your tank's pH would drop over time (a bad thing). With sufficient buffering, the pH stays stable (a good thing). On the negative side, hard tap water often almost always has a large buffering capacity. If the pH of the water is too high for your fish, the buffering capacity makes it difficult to lower the pH to a more appropriate value. Naive attempts to change the pH of water usually fail because buffering effects are ignored.
In freshwater aquariums, most of water's buffering capacity is due to carbonates and bicarbonates. Thus, the terms “carbonate hardness” (KH), “alkalinity” and “buffering capacity” are used interchangeably. Although technically not the same things, they are equivalent in practice in the context of fishkeeping. Note: the term “alkalinity” should not be confused with the term “alkaline”. Alkalinity refers to buffering, while alkaline refers to a solution that is a base (i.e., pH > 7).
How much buffering does your tank need? Most aquarium buffering capacity test kits actually measure KH. The larger the KH, the more resistant to pH changes your water will be. A tank's KH should be high enough to prevent large pH swings in your tank over time. If your KH is below roughly 4.5 dH, you should pay special attention to your tank's pH (e.g, test weekly, until you get a feel for how stable the pH is). This is ESPECIALLY important if you neglect to do frequent partial water changes. In particular, the nitrogen cycle creates a tendency for an established tank's pH to decrease over time. The exact amount of pH change depends on the quantity and rate of nitrates produced, as well as the KH. If your pH drops more than roughly two tenths of a point over a month, you should consider increasing the KH or performing partial water changes more frequently. KH doesn't affect fish directly, so there is no need to match fish species to a particular KH.
Note: it is not a good idea to use distilled water in your tank. By definition, distilled water has essentially no KH. That means that adding even a little bit of acid will change the pH significantly (stressing fish). Because of its instability, distilled (or any essentially pure water) is never used directly. Tap water or other salts must first be added to it in order to increase its GH and KH.
There only some cases where you should use distilled water or RO water in your freshwater tank, if you are keeping fish like discus where they need to have GH as low as 30 to 50 GH.